fig4

Transition from isotropic positive to negative thermal expansion by local Zr<sub>6</sub>O<sub>8</sub> node distortion in MOF-801

Figure 4. (A) PDF patterns of MOF-801 at 300 K (path 1: Zr-O atom pair, path 2: Zr···Zr atom pair, path 3: Zr···Zr atom pair). (B) Schematic diagram of the Zr6O8 node, showing paths 1, 2 and 3, respectively. (C) Temperature-dependent PDF patterns in the range of 1.5-5.5 Å. (D) Illustration of the local Zr6O8 node distortion with temperature.

Microstructures
ISSN 2770-2995 (Online)
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